Product ID:AUTOCOAT LV HARDENER FAST, 004098
MSDS Date:11/16/1998
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLCQG

AKZO NOBEL COATINGS INC

5555 SPALDING DR
NORCROSS, GA 30092
US

Emergency Phone: 800-424-9300

Info Phone: 770-662-8464; 770-441-8628

Cage: AKZNB

AKZO NOBEL COATINGS LTD.

ETOBICOKE, ONTARIO, M9W5S6, ON 30092 CN

Telephone: UNK

Cage: TO942

1.0)

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1.0)

CAS: 100-41-4

RTECS: DA0700000

OSHA PEL 435 MG/M3;100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1.7).

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 710 MG/M3;150 PPM

ACGIH TLV: 713 MG/M3;150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

N. AP.

CAS: 28182-81-2

RTECS: NQ9170000

OSHA PEL N.AV.

ACGIH TLV: 1 MG/M3

HEXAMETHYLENE DIISOCYANATE. (MFR. PROVIDED CAS # 822-06-6).

CAS: 822-06-0

RTECS: MO1740000

OSHA PEL N. AV.

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

AROMATIC SOLVENT. (NO CAS # PROVIDED). (VAPOR PRESSURE

OSHA PEL N. AV.

ACGIH TLV: 100 PPM

C-11 KETONE SOLVENT. (MIXTURE, NO CAS # PROVIDED). (VAPOR

OSHA PEL N AV.

ACGIH TLV: N. AV.

1.1).

CAS: 110-43-0

RTECS: MJ5075000

OSHA PEL 465 MG/M3;100 PPM

ACGIH TLV: 233 MG/M3;50 PPM

1.2).

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 100 PPM

ACGIH TLV: 188 MG/M3;50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:N/P.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CONTAINS TOULENE WHICH APPEARS ON THE
NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. SEEK
CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING SAFE
HANDLING AND EXPOSURE INFORMATION (F P N). ACUTE: INHALATION:
NASAL/RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA,
HEADACHE, BRONCHITIS, BRONCHIAL SPASMS, PULMONARY EDEMA, ASTHMATIC
CONDITIONS, REDUCED LUNG FUNCTION, POSSI BLE UNCONSCIOUSNESS, CHEM
PNEUMONITIS, CNS DEPRESSION AND EVEN ASPHYXIATION. SKIN CONTACT:
EXTRACTION OF NATURAL OILS WITH RESULTING DRY SKIN, IRRITATION,
REDNESS AND DERMATITIS. SOME SOLVENTS MAY PAS S THROUGH SKIN INTO
(OVEREXPOSURE)
Explanation of Carcinogenicity:ETHYLBENZENE: DRAFT REPORT ON NTP STUDY
STATES LIFETIME INHALATION EXPOSURE OF RATS & MICE TO CONC (750
PPM) RESULTED IN INCREASE IN CERTAIN TYPES OF CANCER, INCLUDING
KIDNEY TUMORS IN RATS & LUNG & L IVER TUMORS IN MICE. EFFECTS WERE
NOT OBSERVED IN ANIMALS EXPOSED TO LOWER CONC (75 PPM OR 250 PPM).
REPORT DOES NOT ADDRESS THE RELEVEANCE OF RSLTS TO HUMANS.
Effects of Overexposure:NAUSEA, COUGH, DIZZINESS, WEAKNESS, HEADACHE,
CHEST PAIN, LACK OF COORDINATION, SHORTNESS OF BREATH, DERMATITIS,
REDNESS &/OR PAIN IN EYES. HLTH HAZARD ACUTE/CHRONIC :THE BLOOD.
EYE CONTACT: IRRITATIO N, REDNESS, PAIN, BLURRED VISION, SENSATION
OF SEEING HALOS AROUND LIGHTS AND REVERSIBLE DAMAGE. INGEST:
GASTROINTESTINAL IRRITATION, POSSIBLE CORROSIVE ACTION TO DIGEST
TRACT, NAUSEA, VOMITING & DIA RRHEA. CHRONIC: INHALATION:
SENSITIZATION CAUSING BRONCHITIS, BRONCHIAL SPASMS, PULMONARY EDEMA
& ASTHMATIC CONDITIONS. DECREASE IN LUNG FUNCTION, PERMANENT LUNG
DAMAGE, KIDNEY, LIVER, & CARDIAC DISOR DERS, RED BLOOD CELL &
(FEDERAL REGS)
Medical Cond Aggravated by Exposure:ISOCYANATE SENSITIZATION, LUNG
DISORDERS, SKIN DISORDERS.

First Aid:INHALATION: MOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF
NECESSARY. ASTHMA LIKE CONDITIONS MAY BE IMMEDIATE OR DEVELOP IN
SEVERAL HOURS. TREAT SYMPTOMATICALLY. SKIN: REMOVE CONTAMINATED
CLOTHING, WASH WITH SOAP & WATER OR RECOGNIZED SKIN CLEANER. DO
NOT USE SOLVENTS OR THINNERS. TREAT SYMPTOMATICALLY. EYE: CONTACT
LENSES MUST BE REMOVED. FLUSH WITH WATER FOR AT LEAST 15 MINUTES,
CONSULT A PHY SICIAN IMMEDIATELY. INGESTION: DRINK ONE OR TWO
GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. TREAT
SYMPTOMATICALLY. IN ALL CASES IF SYM PTOMS PERSIST, SEEK MEDICAL
ATTENTION.

Flash Point Method:SCC
Flash Point:=25.6C, 78.F
Lower Limits:0.9
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL OR WATER FOG OR
SPRAY. WATER JET OR STREAM IS UNSUITABLE. NFPA FLAMMABILITY: IB.
Fire Fighting Procedures:USE NIOSH APPROVED SELF- CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . WATER SHOULD BE USED TO
COOL CONTAINERS EXPOSED TO FIRE. FLAMMABLE LIQUID. REFER TO GUIDE
127 OF THE NORTH AMERICAN EMERGENCY GUIDE BOOK.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. FORMS EXPLOSIVE MIXTURE WITH AIR. VAPORS
ARE HEAVIER THAN AIR &MAY TRAVEL TO SOURCE OF IGNITION & FLASH
BACK. FIRE WILL PRODUCE DENSE BLACK SMOKE CONTAINING HAZARDOUS
PRODUCTS OF COMBUSTION. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT.
OBTAIN MEDICAL ATTENTION.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID
BREATHING VAPORS, VENTILATE CONFINED AREA. DIKE TO REDUCE EXTENT OF
SPILL. REMOVE WITH INERT ABSORBENT (VERMICULITE, CLAY, OIL-DRY,
KITTY LITTER, ETC) USING NON-S PARKING TOOLS. TRANSFER TO GROUNDED
METAL CONTAINER. SEAL CONTAINER. DISPOSE OF AS HAZARDOUS WASTE. IF
NECESSARY REPORT TO APPLICABLE GOVERNMENT AGENCY.

Handling and Storage Precautions:DO NOT HANDLE UNTIL THE MANUFACTURER'S
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. REGULATIONS
REQUIRE THAT ALL EMPLOYEES BE TRAINED ON MATERIAL SAFETY DATA
SHEETS FOR ALL PRODUCTS WITH WHICH TH EY COME IN CONTACT. USE
APPROVED BONDING AND GROUNDING PROCEDURES WHEN TRANSFERRING (OTHER
PREC)
Other Precautions:VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG
FLOORS. MATERIAL HAS AN OFFENSIVE ODOR. PROLONGED EXPOSURE MAY
REDUCE THE USER'S SENSITIVITY TO THE ODOR, THUS REDUCING THE
EFFECTIVENESS OF ODOR AS A WARNING AGAINST EXPOSURE. HNDLG/STORAGE
(CONT'D): LIQUID TO ANOTHER CONTAINER. DO NOT TRANSFER TO UN
LABELED (TRANSPORT)

Respiratory Protection:PRODUCT CONTAINS ISOCYANATES. USE NIOSH APPROVED
POSITIVE PRESSURE AIR SUPPLY RESPIRATOR. WHEN PERSONNEL, WHETHER
SPRAYING OR NOT, ARE INSIDE A SPRAY BOOTH, VENTILATION IS UNLIKELY
TO BE SUFFICIENT TO CONTROL PARTICULATES AND CHEMICAL VAPOR IN ALL
CASES. IN SUCH CASES AIR SUPPLIED RESPIRATORY EQUIP IS REQUIRED
UNTIL PARTICULATE AND VAPOR (SARA)
Ventilation:PROVIDE SUFFICIENT VENTILATION TO KEEP VAPOR CONCENTRATION
BELOW THE GIVEN TLV AND/OR PEL. FOR BAKING FINISHES, EXHAUST VAPORS
EMITTED DURING (SARA)
Protective Gloves:SOLVENT RESISTANT GLOVES ARE REQUIRED FOR PROLONGED
OR REPEATED (SARA)
Eye Protection:ANSI APPROVED SAFETY GOGGLES & FULL FACE SHIELD . USE
(OTHER INFORMATION)
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . CHEMICAL RESISTANT APRON, BOOTS, OR OTHER
CLOTHING IF NEEDED TO AVOID REPEATED OR FREQUENT CONTACT.
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE IN WORK AREA. WASH
HANDS BEFORE EATING, SMOKING, OR USING WASHROOM. LAUNDER CLOTHING
BEFORE REUSE.
Supplemental Safety and Health
IN CASES WHERE NO MONITORING FOR AIRBORNE CONTAMINANT HAS BEEN CARRIED
OUT, ASSUME MAXIMUM EXPOSURE & USE ANTISTATIC PAINT SUIT, GOGGLES,
GLOVES, & NIOSH APPROVED AIR SUPPLIED RESPIRATORY EQUIP. LIQUI D
MAY PENETRATE SHOE & LEATHER CAUSING DELAYED IRRITATION. ALL
PERSONAL PROT EQUIP SHOULD MEET NIOSH/OSHA REQUIREMENTS.

Boiling Pt:=122.2C, 252.F
B.P. Text:252-340F.
Vapor Density:> AIR
VOC Grams/Liter:2.6
Evaporation Rate & Reference:SLOWER THAN ETHER.
Appearance and Odor:CLEAR LIQUID. OFFENSIVE ODOR.
Percent Volatiles by Volume:37

Stability Indicator/Materials to Avoid:YES
AKALIS, OXIDIZERS, ALKALI METALS, WATER, AMINES, ACIDS, SODIUM
HYPOCHLORITE, METAL COMPOUNDS.
Stability Condition to Avoid:STABLE UNDER NON-EMERGENCY CONDITIONS.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN, VARIOUS
HYDROCARBONS, HYDROGEN CYANIDE, HEXAMETHLENE DIISOCYANATE (HDI).
Conditions to Avoid Polymerization:MAY OCCUR. AVOID OPEN FLAMES, HEAT,
SPARKS, MOISTURE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL POLLUTION REQUIREMENTS. IN ADDITION, RAGS, SPRAY BOOTH
FILTERS, PAINT SUITS, EMPTY CANS, ETC., CONTAMINATED WITH PRODUCT
MAY BE HAZARDOUS WASTE. DETERMINE WHETHER CONTAMINATED ITEMS ARE
HAZARDOUS AND DISPOSE OF AS APPROPRIATE. CLEAN PREFERABLY W ITH A
DETERGENT, AVOID THE USE OF SOLVENTS.

Toxicological Information:THRESHOLD LIMIT VALUE: NONE ESTABLISHED FOR
THIS PRODUCT. XYLENE-MIXED ISOMARS: CAS # 1330-20-7: LD50 ORAL:
4300, LD50 DERMAL: >1700, LC50 INHALATION: 5000. ETHYLBENZENE:
CAS# 100-41-4: LD50 ORAL: 35 00, LD50 DERMAL: 15486, LC50
INHALATION: N.AV. BUTYL ACETATE, CAS# 123-86-4: LD50 ORAL: 10768,
LD50 DERMAL: 17600, LC50 INHALATION: 2200. POLYHEXAMETHYLENE
DIISOCYANATE, CAS# 28182-81-2: LD50 ORAL: N. AV., LD50 DERMAL:
N.AV., LC50 INHALATION: 18500. HEXAMETHYLENE DIISOCYANATE, CAS#
822-06-6: LD50 ORAL: 738, LD50 DERMAL: 593, LC50 INHALATION: 30.
AROMATIC SOLVENT: LD50 ORAL, LD50 DERMAL, LC50 INHALA TION: N/AV.
C-11 KETONE (ECOLOGICAL)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:N/P. TOXICOLOGICAL INFORMATION (CONT'D): SOLVENT: LD50 ORAL:
3200. LD50 DERMAL, LC50 INHALATION. METHYL AMYL KETONE, CAS#
110-43-0: LD50 ORAL: 1670, LD50 DERMAL: 10286, LC50 INHALATION:
2000. TOLUENE, CAS# 108-88-3: LD50 ORAL: 5000, LD50 DERMAL: 14000,
LC50 INHALATION: 4000.

Transport Information:TRANSPORT CLASS: UN1263. SHIPPING NAME; PAINT.
RELATED MATERIAL PACKING GROUP: III. FOR CANADIAN TRANSPORTATION
EMERGENCIES CALL: CANUTEC: 613-996-6666. OTHER PRECAUTIONS
(CONT'D): CONTAINERS. CLOSE ALL CONTAINERS TIGHTLY AFTER EACH USE.
DO NOT SMOKE, EAT, OR DRINK IN WORK AREA. STORE PLASTIC CONTAINERS
OF FLAMMABLE LIQUIDS INSIDE CLOSED, APPROVED BOXES OR SAFETY
CABINETS. STORE CONTAINERS OUT O F SUN AND AWAY FROM HEAT, SPARKS,
OPEN FLAMES, AND ELECTRICAL EQUIPMENT. CONSULT NFPA AND LOCAL CODES
FOR ADDITIONAL STORAGE REQUIREMENTS. WHEN HANDLING WEAR AN ORGANIC
VAPOR CARTRIDGE RESPIRATOR (NIO SH/OSHA).

SARA Title III Information:INGREDIENTS SUBJECT TO SECTION 313 OF EPCRA
OF 1986: XYLENE-MIXED ISOMARS, CAS # 1330-20-7; ETHYLBENZENE, CAS #
100-41-4; HEXAMETHLENE DIISOCYANATE, CAS # 822-06-6; TOLUENE, CAS #
108088-3. RESP PROT (CONT'D): CONCENTRATION HAS FALLEN BELOW
EXPOSURE LIMITS. SEE SAFETY EQUIPMENT SUPPLIER FOR EVALUATION AND
RECOMMENDATION. VENTILATION (CONT'D): HEATING. REMOVE DECOMPOSITION
PRODUCTS FORMED DURING WE LDING OR FLAME CUTTING OF SURFACES COATED
WITH THIS PRODUCT. GLOVES (CONT'D): CONTACT. BARRIER CREAMS ARE NOT
SUBSTITUTES FOR FULL PHYSICAL PROTECTION. REFER TO SAFETY EQUIPMENT
SUPPLIER FOR EFFECTIVE GLOVE RECOMMENDATIONS.
Federal Regulatory Information:N/P. SIGNS/SYMPTOMS OF OVEREXPOSURE:
LEUKOCYTE DISORDERS WHICH MAY RESULT IN ANEMIA. SKIN CONTACT:
SENSITIZATION TO SKIN MAY OCCUR, CAUSING REDNESS, IRRITATION AND
DERMATITIS. EYE CONTACT: MAY RESULT IN CORNEAL OPACITY (CLOUDING
OF EYE SURFACE). INGESTION: KIDNEY DAMAGE,BLOOD SYSTEM DAMAGE.
OTHER HEALTH EFFECTS: INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALING CONTENTS MAY BE HARMFUL OR FATAL.
REPORTS HAVE ASSOCIATED REPEATED/PROLONGED OCCUPATIONAL
OVEREXPOSURE WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
State Regulatory Information:WARNING: THIS PRODUCT CONTAINS A CHEMICAL
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS
OR OTHER REPRODUCTIVE HARM: TOLUENE.